{"id":54270,"date":"2026-06-19T12:38:48","date_gmt":"2026-06-19T09:38:48","guid":{"rendered":"https:\/\/www.tktk.ee\/uudised\/ppe-and-the-hidden-threat-of-combustion-products\/"},"modified":"2026-06-22T13:20:16","modified_gmt":"2026-06-22T10:20:16","slug":"ppe-and-the-hidden-threat-of-combustion-products","status":"publish","type":"uudised","link":"https:\/\/www.tktk.ee\/en\/news\/ppe-and-the-hidden-threat-of-combustion-products\/","title":{"rendered":"PPE and the hidden threat of combustion products"},"content":{"rendered":"\n<p class=\"wp-block-paragraph\"><strong>Every shift, firefighters enter environments laced with a complex cocktail of toxic combustion products \u2014 PAHs, volatile organic compounds, heavy metals, and more. Their suits protect against heat and flame. But do they protect against the chemicals?<\/strong><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">The fourth ECPC 2027 webinar <em>PPE and Protection Against the Ingress of Combustion<\/em>, hosted by TTK University of Applied Sciences, confronted that question directly, with findings from the Czech FirePro project presented by <strong>Kamila Lunerova<\/strong> and <strong>Jakub Van\u011bk<\/strong> from <strong>National Institute for NBC Protection<\/strong>, Czech Republic.<br><br>The webinar is part of a series leading up to the <a href=\"https:\/\/ecpc2027.ee\/\" target=\"_blank\" rel=\"noreferrer noopener\">European Conference of Protective Clothing (ECPC2027)<\/a>, which will take place at TTK University of Applied Sciences in May 2027.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><strong>The toxic cocktail firefighters face<\/strong><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Combustion products vary dramatically with what burns. Vegetation fires produce carbon monoxide, VOCs, and PAHs. Modern building fires \u2014 plastics, foams, composites \u2014 generate far more dangerous mixtures: hydrogen cyanide, isocyanates, dioxins, and more. Evidence links firefighting exposures to DNA damage, oxidative stress, and hormonal disruptions, all associated with cancer.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">The project team used polycyclic aromatic hydrocarbons (PAHs) as model contaminants \u2014 the EPA&#8217;s group of 16 compounds, from naphthalene (2 rings) to the highly carcinogenic benzo[a]pyrene (5 rings) \u2014 abundant, measurable, and representative of the broader chemical threat.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><strong>Where do the chemicals get in?<\/strong><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Working with the Technical University of Ostrava, the team sampled firefighters during a real training fire in a plastic-filled interior space. Passive samplers were placed on the garment, in pockets, and on skin under the suit. PAHs were detected under the suit and on skin after interventions as short as 10\u201315 minutes. The moisture barrier proved especially problematic \u2014 acting as a chemical reservoir that slowly releases contaminants toward the skin.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">A toxicology chamber test using yellow indicator underwear \u2014 which turns pink on contact with model gas \u2014 mapped precisely where ingress occurs:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li><strong>Structural (3-layer) suits:<\/strong> Problematic at the hood interface, glove-sleeve and boot-trouser junctions. The belt plays a critical role \u2014 without it, ingress also occurred at the waist and neck.<\/li>\n\n\n\n<li><strong>Wildland (1-layer) suits:<\/strong> The underwear turned pink across virtually the entire body. Naphthalene broke through in under 5 minutes \u2014 no meaningful chemical protection.<\/li>\n\n\n\n<li><strong>Hoods:<\/strong> Five models tested; almost all showed immediate breakthrough. The sole exception was a hood made from activated carbon fabric (ACF). Popular thin aramid\/viscose designs failed entirely.<\/li>\n<\/ul>\n\n\n\n<p class=\"wp-block-paragraph\"><strong>The case for activated carbon fabric<\/strong><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Controlled permeation tests with benzene and naphthalene vapours made the contrast stark: structural suits broke through in 10\u201315 minutes, wildland suits in under 5 \u2014 but adding an ACF layer to either produced no measurable breakthrough within a typical firefighting shift.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">ACF is lightweight, flexible, and textile-like in drape. Compared to spherical carbon adsorbents and carbon mesh fabrics, it offers longer breakthrough delay times. A prototype ACF undergarment eliminated the widespread ingress seen with the wildland suit in toxicology chamber tests.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">A key practical concern: does extra protection mean extra heat strain? Thermal mannequin tests at Brno University of Technology showed virtually identical thermal resistance with and without the ACF layer. Physiological tests on three volunteers in a climatic chamber confirmed no significant increase in heat strain \u2014 and endurance time was actually slightly longer with ACF.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><strong>The decontamination problem<\/strong><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">The most urgent unsolved challenge is cleaning. PAHs are notoriously hard to remove, especially from the moisture barrier membrane. Conventional laundering removes only a fraction; supercritical CO\u2082 extraction performs better but is not yet standard.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">For ACF, the problem is compounded: standard detergents block the micropores that give it protective capacity. After just 10 wash cycles, BET surface area dropped from hundreds of square metres per gram to near zero, and micropore volume collapsed. The material loses its adsorptive function entirely \u2014 a serious obstacle to practical use.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">No current European standards address chemical protection for firefighter suits, leaving manufacturers and certification bodies without clear targets.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><strong>Key conclusions<\/strong><\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Structural suits allow naphthalene penetration within 10 minutes; wildland suits within 5.<\/li>\n\n\n\n<li>An ACF layer \u2014 integrated or worn as an undergarment \u2014 dramatically improves chemical protection without meaningfully increasing heat strain.<\/li>\n\n\n\n<li>Decontamination of PAH-contaminated gear remains inadequate; ACF loses adsorptive capacity after repeated washing.<\/li>\n\n\n\n<li>No EU chemical protection standards exist for firefighter suits.<\/li>\n\n\n\n<li>Educating firefighters and first responders about combustion product risks remains urgently needed.<\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<div style=\"height:25px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<p class=\"wp-block-paragraph\">The webinar is available to watch in full <a href=\"https:\/\/youtu.be\/tLOJSUgladk\" target=\"_blank\" rel=\"noreferrer noopener\">HERE<\/a>.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">The next webinar in the series <strong><em>Improving the thermal protection of cold protective garments by the application of phase change material (PCM) <\/em><\/strong>will take place in September, 2026. Speaker of the webinar is Barbara Pause, webinar is moderated by Professor Ada Traumann. Register for the webinar <a href=\"https:\/\/ecpc2027.ee\/webinars\/\" target=\"_blank\" rel=\"noreferrer noopener\">HERE<\/a>.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Learn more about the <a href=\"ECPC2027%20conference\">ECPC2027 conference<\/a> and the webinar series: <a href=\"https:\/\/ecpc2027.ee\" target=\"_blank\" rel=\"noreferrer noopener\">https:\/\/ecpc2027.ee<\/a> and <a href=\"https:\/\/www.linkedin.com\/company\/espc-european-society-of-protective-clothing\/\" target=\"_blank\" rel=\"noreferrer noopener\">ECPC LinkedIn<\/a>.<\/p>\n\n\n\n<div style=\"height:25px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<p class=\"wp-block-paragraph\">Additional information:<\/p>\n\n\n    <div class=\"nbl-contacts-container nbl-card-layout\">\n\t\t\t\t\t<div class=\"nbl-contact-card\">\n\t\t\t\t\t\t\t\t\t<div class=\"contact-visual contact-cards-upper-line \"><\/div>\n\t\t\t\t\t\t\t\t<div class=\"main\">\n\t\t\t\t\t\n\t\t\t\t\t<div class=\"col\">\n\t\t\t\t\t\t<span class=\"contacts-name\">Paula Veske-Lepp<\/span>\n\t\t\t\t\t<\/div>\n\n\t\t\t\t\t<div class=\"col\">\n\t\t\t\t\t\t<span class=\"margin-bottom-after-occupation\">Visiting Professor<\/span>\t\t\t\t\t<\/div>\n\n\t\t\t\t\t<div class=\"col\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t<span>\n\t\t\t\t\t\t\t\t\t<div class=\"i-wrap\">\n\t\t\t\t\t\t\t\t\t\t<img decoding=\"async\" src=\"\/wp-content\/uploads\/2022\/08\/Icon-ionic-md-mail-open.svg\" alt=\"Email\" aria-hidden=\"true\"\/>\n\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\t\t<a href=\"mailto:paula.veske-lepp@tktk.ee\">paula.veske-lepp@tktk.ee<\/a>\n\t\t\t\t\t\t\t\t<\/span>\n\t\t\t\t\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\t\t\t\t\t\t\t\t<span>\n\t\t\t\t\t\t\t\t<div class=\"i-wrap\">\n\t\t\t\t\t\t\t\t\t<img decoding=\"async\" src=\"\/wp-content\/uploads\/2022\/08\/Icon-material-room.svg\" alt=\"Location\" aria-hidden=\"true\"\/>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\tTLN-A414\t\t\t\t\t\t\t<\/span>\n\t\t\t\t\t\t\n\t\t\t\t\t\t\t\t\t\t\t\t\t<span>\n\t\t\t\t\t\t\t\t<div class=\"i-wrap\">\n\t\t\t\t\t\t\t\t\t<div style=\"width:15px;\"><\/div>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\t<a href=\"https:\/\/www.etis.ee\/CV\/Paula_Veske\/est\/\">CV-ETIS<\/a>\n\t\t\t\t\t\t\t<\/span>\n\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t\n\t\t\t\t<\/div>\n\t\t\t\t\n\t\t\t<\/div>\n\t\t    <\/div>\n","protected":false},"featured_media":52788,"template":"","nd_news_cat":[1902,1906],"uudiste_rubriigid":[],"uudiste_sildid":[],"class_list":["post-54270","uudised","type-uudised","status-publish","has-post-thumbnail","hentry","nd_news_cat-news","nd_news_cat-technology-and-circular-economy"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.8 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>PPE and the hidden threat of combustion products - Tallinna Tehnikak\u00f5rgkool<\/title>\n<meta name=\"description\" content=\"Every shift, firefighters enter environments laced with a complex cocktail of toxic combustion products \u2014 PAHs, volatile organic compounds, heavy metals, and more. Their suits protect against heat and flame. But do they protect against the chemicals? The fourth ECPC 2027 webinar PPE and Protection Against the Ingress of Combustion, hosted by TTK University of Applied Sciences, confronted that question.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.tktk.ee\/en\/news\/ppe-and-the-hidden-threat-of-combustion-products\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"PPE and the hidden threat of combustion products - Tallinna Tehnikak\u00f5rgkool\" \/>\n<meta property=\"og:description\" content=\"Every shift, firefighters enter environments laced with a complex cocktail of toxic combustion products \u2014 PAHs, volatile organic compounds, heavy metals, and more. Their suits protect against heat and flame. 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